FED-STD-791D
Substance
Condition
Reaction
Sulfur Carbon disulfide
friction, impact, heating
explosion
explosion
friction, impact, heating
Organic sulfur, sulfides
Phosphorus red
friction, impact, heating
explosion
explosion
friction, impact, heating
Ammonium rhodanate
Ammonium rhodanate + copper + alcohol
ignition
impact
Hydrazine, hydroxylamine
friction, impact
explosion
Zinc chloride
contact
explosion
Sugar + ferricyanides
letting stand at atmospheric
heat generation
explosion
Sodium hyposulfites
impact
Powder of combustible materials
impact, friction
explosion
explosion
impact, friction
Amines (org, inorg)
impact, friction
explosion
Flammability: Powerful oxidizing material. Forms explosive mixtures with combustible,
organic or other easily oxidizable materials. These mixtures are easily
ignited by friction or heat.
Handling: Protect containers against physical damage. Separate from combustible,
organic or other readily oxidizable materials, acids, ammonium salts, sulfur
and flammable vapors. Avoid storage on wood floors. Immediately remove
and dispose of any spilled chlorate. Wear rubber gloves, face shield and
coverall.
Emergency Treatment and Measures:
a. Hygienic Precautions: Encourage personal cleanliness. Provide instructions to
exposed personnel.
b. First Aid: If swallowed, call a physician.
c. Fire Precautions (In case of outbreak): Flood with water.
Spills:
Cover with weak reducing agents such as hypo, bisulfites or ferrous salts.
Bisulfites or ferrous salts need additional promoter of some 3M-H2SO4 to
accelerate reaction. Transfer the slurry (or sludge) into a large container of
water and neutralize with soda ash. Drain into a sewer with abundant water.
054
Potassium dichromate K2Cr2O7
Synonyms: Potassium bichromate, Red chromate of potash.
Life Hazard: Highly toxic. A recognized carcinogen. A moderate fire hazard by
chemical reaction. A powerful oxidizer. Dust may cause skin and nasal
irritation. Strong solutions can irritate the skin. Hazardous reaction with:
430
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